Lecturer(s)
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Škvorová Magda, Ing. Ph.D.
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Course content
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1. Critical point, critical properties, and their estimation. (Lab: Demonstration of critical point measurement in the laboratory) 2. State behaviour (SB): theoretical introduction, real gas (intermolecular forces). (Lab: Demonstration of density measurement using a vibrating densitometer) 3. Virial equation of state: pure substances and mixtures. (Lab: Calculations (demonstration of experiment-theory connection) on a PC) 4. Equations of state (EOS) for pure substances and mixtures + principle of corresponding states (PCS), conditions for EOS, mixing rules. 5. PVT behaviour of liquids and empirical relations for estimating of mixtures: Dalton?s and Amagat?s laws. 6. Thermodynamics: review of basic equations and relationships. 7. Thermodynamic properties of ideal gases, reference states. 8. Thermodynamic properties of real gases: excess properties and relationships for their calculation. 9. Heat and work calculation in various processes. (Lab: Solving more complex examples on a PC) 10. Partial molar properties. (Lab: Measuring properties in an alcohol-water mixture) 11. Thermodynamics of mixtures: mixing and excess properties. 12. Phase equilibrium: introduction and pure substances. (Lab: Calculation and measurement of pure substance vapour pressure) 13. Vapour-liquid equilibrium (VLE). (Lab: VLE measurement and PC calculations) 14. Student project presentations and evaluation.
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Learning activities and teaching methods
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unspecified, unspecified, unspecified
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Learning outcomes
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This course builds on the knowledge gained in physical chemistry. It aims to demonstrate the practical application of theoretical concepts to real-world problems. Teaching is supported by the use of computer software such as EXCEL and Matlab, as well as modern laboratory instruments. To pass the course, students are required to complete and present an assigned project.
Students extend their knowledge obtained from general and physical chemistry. They are supposed to be able to apply the new skills to solve chemical-engeneering problems with the main focus on thermodynamics and phase behaviour of fluids.
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Prerequisites
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No preceding course is required. Students are expected to understand lectures and recommended textbooks and should be able to speak and write in English. The high school knowledge of mathematics, physics and chemistry is expected.
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Assessment methods and criteria
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unspecified
Students are expected to thoroughly understand the subject matter as presented in the lectures. They are also required to complete assigned projects and present their results to demonstrate their understanding and practical application of the concepts.
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Recommended literature
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Atkins P. W. Physical Chemistry, 6th ed., Oxford University Press, Oxford 2001..
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Atkins P. W. Elements of Physical Chemistry, Oxford University Press, 2016.
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J. Ghmeling a spol. Chemical Thermodynamics for process simulation, Wiley-VCH Verlag 2012.
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