st to 3rd weeks: FCH repetition (latent states, thermodynamics, phase equilibria). 4th - 6th weeks: Surface chemistry. Classification, basic terms. Phase interfaces, classification and characteristics. Intermolecular interactions, molecules in the phase interface, eg When depositing nanostructures on the substrate surface, cell adhesion. Interface: surface and interfacial energy. 2 phases, 3 phases. Surface properties (curved interfaces, wetting, cohesion, adhesion, small structures and thin films on a solid substrate,?). Influence of interface on TD properties. Determination of contact angle. 7th week: Solid surfaces. A change in the surface properties of a material in relation to its size, from micro- to nano-. Calculation of Au density, change of thawing and other properties. 8th week: Adsorption, phase interfaces - gas / liquid, gas / solid, Gibbs adsorption isotherm, adsorption isotherms and models (Freundlich, Langmuir, BET). BET adsorption, desorption, pore shapes. Pore ??distribution. 9th week: Electrical properties of phase interfaces. Electrokinetic effects, electric double layer, zeta potential. Correlation of surface properties. 10th week: Adhesion of nanostructures, adhesion of cells. Preparation of nanostructured materials. 11th - 13th weeks: Dispersion systems: classification: colloid, sol, gel, foam, emulsion, aerosol; macromolecule solutions; micelles, surface films. Dispersion systems - phenomena: forces between colloidal particles; sedimentation, electrokinetic phenomena, rheology, optical properties; stability of colloidal systems. Colloidal solutions of high molecular weight compounds and their properties. 14th week: Transport phenomena. Diffusion, electrical conductivity, heat conduction, viscosity.
|
-
ADAMSON, A. W., GAST, A. P. Physical Chemistry of Surfaces. John Wiley & Sons, Inc., New York, 1997.
-
BARTOVSKÁ, L., ŠIŠKOVÁ, M. Co je co v povrchové a koloidní chemii. VŠCHT Praha, 2005.
-
BARTOVSKÁ, L., ŠIŠKOVÁ, M. Fyzikální chemie povrchů a koloidních soustav. VŠCHT, 2010.
-
BIRDI, K. S. Handbook of Surface and Colloid Chemistry. CRC Press, New York, 1997.
-
MILLING, A. J. Surface Charakterization Methods. Marcel Dekker, Inc., New York, 1999.
-
POUCHLÝ, J. Fyzikální chemie makromolekulárních a koloidních soustav. VŠCHT Praha, 2008.
|